BaCN2

Chemical Formula BaCN2
Composition Formula BaCN2
Crystal System Tetragonal
Space Group 140_I4/mcm
Lattice Parameter a = 6.0249(4) Å
b = 6.0249(4) Å
c = 7.1924(5) Å
α = 90°
β = 90°
γ = 90°
Characteristic

 BaCN2の新規多形

Synthesis Route

BaCO3をアンモニア気流中で1173K15時間焼成

Properties

BaNCN基と正方逆プリズム型の多面体を形成

Applications

蛍光体母体

References

 “Red-emission over a wide range of wavelength at various temperatures from tetragonal BaCN2:Eu2+” Y. Masubuchi, S. Nishitani, A. Hosono, Y. Kitagawa, J. Ueda, S. Tanabe, H. Yamane, M. Higuchi, S. Kikkawa, Journal of Materials Chemistry C, (2018) in press. (DOI: 10.1039/C8TC01289J)

Keywords
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